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Can the world make the chemicals it needs without oil?

September 20, 2019
Chemical Value Chain

Black, gooey, greasy oil is the starting material for more than just transportation fuel. It’s also the source of dozens of petrochemicals that companies transform into versatile and valued materials for modern life: gleaming paints, tough and moldable plastics, pesticides, and detergents. Industrial processes produce something like beauty out of the ooze. By breaking the hydrocarbons in oil and natural gas into simpler compounds and then assembling those building blocks, scientists long ago learned to construct molecules of exquisite complexity.

Fossil fuels aren’t just the feedstock for those reactions; they also provide the heat and pressure that drive them. As a result, industrial chemistry’s use of petroleum accounts for 14% of all greenhouse gas emissions. Now, growing numbers of scientists and, more important, companies think the same final compounds could be made by harnessing renewable energy instead of digging up and rearranging hydrocarbons and spewing waste carbon dioxide (CO2) into the air. First, renewable electricity would split abundant molecules such as CO2, water, oxygen (O2), and nitrogen into reactive fragments. Then, more renewable electricity would help stitch those chemical pieces together to create the products that modern society relies on and is unlikely to give up.

“This is very much a topic at the forefront right now,” says Daniel Kammen, a physicist at the University of California, Berkeley.

Chemists in academia, at startups, and even at industrial giants are testing processes—even prototype plants—that use solar and wind energy, plus air and water, as feedstocks. “We’re turning electrons into chemicals,” says Nicholas Flanders, CEO of one contender, a startup called Opus 12. The company, located in a low-slung office park in Berkeley, has designed a washing machine–size device that uses electricity to convert water and CO2 from the air into fuels and other molecules, with no need for oil. At the other end of the commercial scale is Siemens, the manufacturing conglomerate based in Munich, Germany. That company is selling large-scale electrolyzers that use electricity to split water into O2 and hydrogen (H2), which can serve as a fuel or chemical feedstock. Even petroleum companies such as Shell and Chevron are looking for ways to turn renewable power into fuels.

Changing the lifeblood of industrial chemistry from fossil fuels to renewable electricity “will not happen in 1 to 2 years,” says Maximilian Fleischer, chief expert in energy technology at Siemens. Renewable energy is still too scarce and intermittent for now. However, he adds, “It’s a general trend that is accepted by everybody” in the chemical industry.

> View the full article on the Science website

By Robert F. Service

Source: Science

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