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Lithium-ion batteries go cobalt free

July 23, 2020
Chemical Value Chain

Commercial lithium-ion batteries have always relied on cathodes that contain cobalt, but the expensive metal’s supply chain is fraught with issues.

A new cobalt-free cathode could provide reprieve (Adv. Mater. 2020, DOI: 10.1002/adma.202002718). What’s more, in lab tests, lithium-ion battery cells made with the new cathode held more energy over hundreds of charge cycles than commercial ones.

Battery cathode materials are layered crystals of lithium metal oxides. The metal is usually a mix of nickel, cobalt, aluminum, and manganese. Nickel alone would give the most energy-dense batteries, meaning cars with longer driving range, but it is unstable and reactive. Cobalt is

key for boosting energy density and battery life because it keeps the layered structure stable as lithium ions get reversibly stuffed into and extracted from the cathode during battery operation.

Most of today’s electric vehicle batteries use nickel-manganese-cobalt cathodes, with 60% nickel and 20% each of cobalt and manganese. Researchers are working on pushing nickel up to 80% and bringing the other metals down to 10% each.

But some carmakers want to eliminate cobalt entirely, given its scarcity and ethical considerations around mining the metal. Around two-thirds of the world’s cobalt mining happens in the Democratic Republic of Congo, where operations are linked to human rights and environmental abuses. Cobalt-free cathodes made so far, though, have lagged in performance and have not been tested in practical cells—until now.

Arumugam Manthiram, a solid state chemist at the University of Texas at Austin, and his colleagues made a high-performance, cobalt-free cathode material that is 89% nickel, with aluminum and manganese comprising the rest. Making a layered crystal with an even distribution of metal ions is key to a good cathode, but without the help of cobalt, it has proven difficult, Manthiram says. “The ions tend to segregate, so you won’t get performance,” he explains.

The UT Austin team was able to get a uniform distribution by carefully controlling their chemical synthesis. They first mix aqueous solutions of nickel, manganese, and aluminum salts. Then they add potassium and ammonium hydroxide to maintain a precise pH and heat to a controlled temperature of 50°C. This forces the metal hydroxides to precipitate out of the solution together, keeping the ions evenly distributed. The precipitate is then filtered, mixed with lithium hydroxide, and heated until it sinters into 12 µm spheres of the final cathode material.

The researchers made battery pouch cells with the new cathode and a commercial graphite anode, and compared it with nickel-manganese-cobalt cathodes. The new cathode battery had higher energy density over 1000 charge cycles. Manthiram and his colleagues have launched a start-up, TexPower, to commercialize the material.

K.M. Abraham, chief technology officer at battery consulting company E-KEM Sciences, says the long-term safety and performance of the new material will need to be assessed using industrial scale cathodes. But he says the work is a very important development. “These investigators appear to have finally achieved the long sought-after cobalt-free cathode,” he says.

By: Prachi Patel

Source: C&EN

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